Wednesday, October 16, 2024

Perovskite photo voltaic cell achieves larger stability with new tin oxide layer – pv journal Worldwide

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Using atomic layer deposition, a analysis staff from the City University of Hong Kong has created an oxygen-deficient tin oxide layer to interchange the extra frequent fullerene electron transport layer in perovskite photo voltaic cells. The result’s a 25%-efficient system that is ready to hold round 95% of its effectivity after 2,000 hours.


Researchers on the City University of Hong Kong (CityUHK) have offered a brand new manufacturing method for perovskite photo voltaic cells.

The staff made two improvements within the construction of perovskite photo voltaic cells. The first includes combining hole-selective supplies and perovskite layers, to simplify the manufacturing course of.

The second includes the substitute of conventional natural supplies, equivalent to fullerene and bathocuproine (BCP)with tin oxide (SnO₂), an inorganic electron transport layer, in a course of generally known as atomic layer deposition (ALD) technique. ALD creates an oxygen-deficient tin oxide layer, which reduces the band offset to a thicker, overgrown layer of regular tin oxide. This has been discovered to considerably enhance the operational stability of a tool.

The work is offered within the paper “Long-term stability of perovskite photo voltaic cells by atomic layer deposition of tin oxide,” which is out there within the journal Science. The analysis staff says their new manufacturing method boosts the commercialization prospects of perovskite photo voltaic cells by bettering sturdiness, reliability, effectivity and affordability.

“The system construction reported on this examine represents probably the most simplified structure within the present subject of perovskite photo voltaic cells, which gives important benefits for industrialization,” stated Gao Danpeng, co-author of the paper. He added that as the answer doesn’t require a conventional natural switch layer, the fabric price of the manufacturing course of is diminished and the manufacturing is simplified.

The analysis paper paperwork how the staff’s fabricated cell achieved an influence conversion effectivity of over 25% after optimizing the oxygen emptiness defects throughout the tin layer oxide. The cell additionally exhibits superior sturdiness in comparison with conventional perovskite photo voltaic cells, because it retains 95% of its effectivity after 2,000 hours of steady operation beneath strict take a look at situations.

The researchers plan for the subsequent part of their analysis to deal with utilizing their new construction in bigger perovskite photo voltaic modules.

“With the potential to implement photo voltaic power techniques throughout the subsequent 5 years, this analysis is a crucial step in the direction of attaining extra sustainable and environmentally pleasant power manufacturing world wide,” stated Professor Zhu Zonglong. in CityUHK’s Department of Chemistry.

The analysis was carried out in collaboration with groups from the National Renewable Energy Laboratory and Imperial College London.

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